Lot's of forums on DivX encoding show complains about audio desynch... or used to. So, it may be related to the movie, and the way that the wav stream(s) have been muxed with video. Then the workaround would be to open the movie with nandub and re-mux with a big value (500ms) for the preroll buffer. It's quite easy and you don't change the quality of the movie if you check "direct stream copy" for all the streams.
Or maybe I'm completely wrong.
What is the bitrate of your movie and the power of your PC?
Do you have the problem with all movies ?
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