Strange issue, can you give more details?
Are you an Administrator of this PC? Did you install BSPlayer or you just use it?
Is this the same BSPlayer in both cases, I mean is it installed in the same directory?
Do you know the codec of the movie? (Look at the properties of the movie in the working login session)
How do you try to run your movie? Do you Double-click on it in an Explorer window or do you load it from inside BSPlayer? Try this latest way (with [L] shortcut) if you didn't. If it doesn't work neither, run \Program Files\Windows Media Player\mplayer2.exe and try to load your movie.
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