Refresh rate it's hardware related and has nothing to do with movie fps, so changing it won't do any good. (25 fps and 85 Hz on a CRT or 60 on a TFT have nothing in common).
On the other hand, if you have a TFT monitor, changing resolution other than native one won't do any good, in fact can only do worse.
If you still want to change resolutions and still have a CRT, in general options you can set "at start" and "in full screen" resolutions.
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